One Piece Season 1, Episode 483 : Looking for the Answer! Fire Fist Ace Dies on the Battlefield!
Ace is punched by a magma fist through and through by Admiral Akainu, and falls into Luffy's arms. He then thinks about his past, and remembers his goal in life: To find out whether or not he had deserved to be born. Akainu proceeds to attack Luffy, but Jinbe stops his advance. Marco and Vista then rush to the aid of Luffy and strike Akainu with Haki imbued attacks, but realize they are ineffective against the Admiral. As everyone else stares in shock at Ace's wounds, they deduce that his organs were burned beyond help, and tell Luffy that Ace will not make it. Just as Ace dies, he thanks Luffy for everything and everyone for loving him. Luffy is then seen crying for the loss of his brother.
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