One Piece Season 1, Episode 334 : The Red Hot Decisive Battle! Luffy vs. The Scorching Don!
The Heat Heat Fruit gives the Don all sorts of powers, from throwing blasts of heat, heating his skin to extreme temperatures, to even being able to fly by blowing steam out his nose. How can Luffy win when he can barely even hit his enemy? Meanwhile, Puzzle defeats Canpacino, the rest of the Straw Hats search for their flag, and Robin and Lil reconcile with one another. Outside, the fight really heats up when Luffy activates Gear Second, but the Don isn't going to fall so easily.
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