Pokemon Season 14, Episode 58 : A Call for Brotherly Love!
While in Driftveil City, Ash and friends run into Cilan's brother Chili. Chili has also left the Striaton Gym so he can improve as a trainer. He and Cilan have a battle which ends with Cilan's victory. Following the battle Chili and Pansear blame each other for the loss and the two end up in a fight. Pansear takes off leading to everyone searching for it. Meanwhile, Pansear is determined to become stronger and prove itself.
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